Selective separation of dyes by green composite membrane based on polylactide with carboxylated cellulose microfiber from empty fruit bunch

A bio-based membrane was prepared by a non-solvent induced phase separation process. A polylactide (PLA)/poly(butylene adipate-co-terephthalate) (PBAT) polymer blend was mixed with functionalized cellulose microfiber from empty fruit bunch (EFB) modified with maleic anhydride (MEFB). MEFB reduced the water contact angle and increased the porosity of the membrane. In a batch adsorption process, the pseudo-second order and Langmuir isotherm models best described the adsorption of the cationic dye methylene blue (MB) on PLA/PBAT and PLA/PBAT-MEFB membranes. In a dynamic adsorption process, pure water flux was higher through the PLA/PBAT-MEFB membrane (1214 L m^-2 h^-1) than the PLA/PBAT membrane (371 L m^-2 h^-1). The PLA/PBAT-MEFB membrane removed 97.2 % of MB while the PLA/PBAT membrane removed only 58.7 %. The hydrophilicity of the membrane and its adsorption efficiency toward MB were improved by the abundant carboxyl groups in MEFB. A filtration test using a mixed dye solution of anionic methyl orange (MO) and MB showed that the PLA/PBAT-MEFB membrane rapidly adsorbed MB while permitting MO to pass through. Moreover, this membrane could be easily regenerated and maintained a satisfactory separation performance over several cycles. Based on the membrane performance and its economical preparation, the proposed biocomposite membrane could be used for selective filtration and wastewater treatment.